DRKSpider is an Open Source web site link validation tool.
DRKSpider will navigate a web site from the URL given, checking internal (and external) links, style sheets, images and other files. Broken links will be reported and the site map displayed in a tree control.
To start a site scan, use the New command from the File menu. Then, insert the starting URL of the site you wish to scan and modify any scan limit you need to. Finally, press Start button.
Follow this link to get step by step explanation.